Rapid Ring-Opening Metathesis Polymerization of Monomers Obtained from Biomass-Derived Furfuryl Amines and Maleic Anhydride.
Rapid Ring-Opening Metathesis Polymerization of Monomers Obtained from Biomass-Derived Furfuryl Amines and Maleic Anhydride.
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DOI：
10.1002/cssc.201900748
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发表时间：
2019-06
期刊：
影响因子：
8.4
通讯作者：
A. Blanpain;J. Clark;T. Farmer;Yuanlong Guo;Ian D. V. Ingram;John E Kendrick;S. Lawrenson;M. North;George F. Rodgers;A. Whitwood
中科院分区：
文献类型：
--
作者：
A. Blanpain;J. Clark;T. Farmer;Yuanlong Guo;Ian D. V. Ingram;John E Kendrick;S. Lawrenson;M. North;George F. Rodgers;A. Whitwood
Well-controlled and extremely rapid ring-opening metathesis polymerization of unusual oxanorbornene lactam esters by Grubbs third-generation catalyst is used to prepare a range of bio-based homo- and copolymers. Bio-derived oxanorbornene lactam monomers were prepared at room temperature from maleic anhydride and secondary furfuryl amines by using a 100 % atom economical, tandem Diels-Alder lactamization reaction, followed by esterification. Several of the resulting homo- and copolymers show good control over polymer molecular weight and have narrow molecular weight distributions.
