A facile Pd(0)-catalyzed regio- and stereoselective diamination of conjugated dienes and trienes
A facile Pd(0)-catalyzed regio- and stereoselective diamination of conjugated dienes and trienes
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DOI：
10.1021/ja0680562
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发表时间：
2007-01-31
影响因子：
15
通讯作者：
Shi, Yian
中科院分区：
文献类型：
--
作者：
Du, Haifeng;Zhao, Baoguo;Shi, Yian
以二叔丁基二氮丙啶酮为氮源，Pd（PPh3）（4）为催化剂，研究了二氮丙啶酮二胺化反应的新工艺。各种共轭二烯和三烯可以在短的反应时间内以良好的产率和高的区域选择性和立体选择性有效地二胺化。
This paper describes a novel diamination process using di-t-butyldiaziridinone as the nitrogen source and Pd(PPh3)(4) as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities in short reaction time.