Carbohelicenes, Heterohelicenes and Related Systems - Some Aspects of Synthesis and Reactions
Carbohelicenes, Heterohelicenes and Related Systems - Some Aspects of Synthesis and Reactions
复制标题
碳螺旋烯、杂螺旋烯和相关系统 - 合成和反应的一些方面
DOI：
10.5059/yukigoseikyokaishi.52.1020
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发表时间：
1994
影响因子：
0.2
通讯作者：
Hitomi Suzuki
中科院分区：
文献类型：
--
作者：
Hideji Osuga;Hitomi Suzuki
螺烯是一类具有刚性螺旋度和高光学稳定性的稠环芳香族化合物，自1955年纽曼和Lednicer首次合成并拆分螺烯以来，螺烯因其独特的结构特征和高旋光度而引起了人们的广泛关注。本文综述了螺烯化学的发展和现状，重点介绍了螺烯和杂螺烯的合成、光学拆分和反应。还包括一些螺烯类似物，如双螺烯、双螺烯、螺环烯和环烯。
Helicenes are a class of helically condensed polycyclic aromatic compounds, which are characterized by the rigid helicity and high optical stability, Since the first synthesis and optical resolution of [6] helicene by Newman and Lednicer in 1955, the chemistry of helicenes has attracted continuing attention because of their unique structural features and high rotational values. The purpose of this article is to make a survey of the development and present situation of helicene chemistry, emphasis being placed on the synthetic aspects, optical resolution and reactions of helicenes and heterohelicenes. Also included are some of helicene analogues such as double helicenes, bihelicenes, propelicenes and circulenes.