Iron-catalysed Negishi coupling of benzyl halides and phosphates
Iron-catalysed Negishi coupling of benzyl halides and phosphates
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DOI：
10.1039/b818961g
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发表时间：
2009-01-01
影响因子：
4.9
通讯作者：
Wilkinson, Mark C.
中科院分区：
文献类型：
--
作者：
Bedford, Robin B.;Huwe, Michael;Wilkinson, Mark C.
含1,2-二（二苯基膦）苯或1,3-二（二苯基膦）丙烷的铁基催化剂在芳基锌试剂与一系列卤代苯和磷酸盐的根岸偶联中具有优异的活性和良好的选择性。
Iron-based catalysts containing either 1,2-bis(diphenylphosphino)benzene or 1,3-bis(diphenylphosphino)propane give excellent activity and good selectivity in the Negishi coupling of aryl zinc reagents with a range of benzyl halides and phosphates.