Synthesis and Diels-Alder reactions of 1,2-dimethylene[2.n]metacyclophanes.
Synthesis and Diels-Alder reactions of 1,2-dimethylene[2.n]metacyclophanes.
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DOI：
10.1021/ol0483403
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发表时间：
2005-01
期刊：
影响因子：
5.2
通讯作者：
T. Yamato;Shinpei Miyamoto;T. Hironaka;Yoshinori Miura
中科院分区：
文献类型：
--
作者：
T. Yamato;Shinpei Miyamoto;T. Hironaka;Yoshinori Miura
1，2-二亚甲基[2.n]MCPs(MCP=偏环芳烃)与合适的二烯烃分子发生Diels-Alder反应，然后芳构化，光诱导或FeCl3诱导的跨环环化反应得到菲取代的多环芳烃，在固体状态下呈螺旋手性。
The Diels-Alder reaction of 1,2-dimethylene[2.n]MCPs (MCP = metacyclophane) with suitable dienophiles followed by aromatization and photoinduced or FeCl(3)-induced transannular cyclization afforded phenanthrene-anellated polycyclic aromatic hydrocarbons, which were found to adopt helical chirality in the solid state.