Metal centre effects on HNO binding in porphyrins and the electronic origin: metal's electronic configuration, position in the periodic table, and oxidation state
Metal centre effects on HNO binding in porphyrins and the electronic origin: metal's electronic configuration, position in the periodic table, and oxidation state
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DOI：
10.1039/c2cc31016c
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发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Zhang, Yong
中科院分区：
文献类型：
--
作者：
Yang, Liu;Fang, Weihai;Zhang, Yong
HNO在有机金属和生物无机化学中与许多不同的金属结合。为了帮助理解实验观察到的金属中心效应，进行了量子化学研究，首次揭示了金属中心特征和电子起源的明确一般结合趋势。
HNO binds to many different metals in organometallic and bioinorganic chemistry. To help understand experimentally observed metal centre effects, a quantum chemical investigation was performed, revealing clear general binding trends with respect to metal centre characteristics and the electronic origin for the first time.