Guest-induced SC-SC transformation within the first K/Cd heterodimetallic triazole complex: a luminescent sensor for high-explosives and cyano molecules
Guest-induced SC-SC transformation within the first K/Cd heterodimetallic triazole complex: a luminescent sensor for high-explosives and cyano molecules
复制标题
第一个 K/Cd 异二金属三唑配合物中客体诱导的 SC-SC 转化：用于高炸药和氰基分子的发光传感器
DOI：
10.1039/c6cc09566f
复制
发表时间：
2017
影响因子：
4.9
通讯作者：
Wang Zhong-Liang
中科院分区：
文献类型：
--
作者：
Wang Ying;Jia Wei;Chen Ran;Zhao Xiao-Jun;Wang Zhong-Liang
第一个基于三唑的 K/Cd 异二金属配合物 {[Cd1.5(TTPE)1.5Cl3K(H2O)3]·3H2O}n (1b) 是在不可逆 SC-SC 转化的离子和溶剂交换实验中由 {[Cd(TTPE)(HCOO)](NO3)·3DMAC·H2O}n (1) 生成的。基于其发光特性，我们首次证明1b是一种异质双金属传感器，用于检测高爆炸药和氰基分子。
The first K/Cd heterodimetallic complex {[Cd1.5(TTPE)1.5Cl3K(H2O)3]·3H2O}n (1b) based on triazole has been generated from {[Cd(TTPE)(HCOO)](NO3)·3DMAC·H2O}n (1) during the ion- and solvent-exchange experiment in an irreversible SC–SC transformation. Based on its luminescence properties, we have, for the first time, demonstrated that 1b is a heterodimetallic sensor for detection of high-explosives and cyano molecules.