The Reversible Dissociation of t-Butyl Esters. Structural Effects and Reactions Mechanism
The Reversible Dissociation of t-Butyl Esters. Structural Effects and Reactions Mechanism
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DOI：
10.1021/ja01187a081
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发表时间：
1948-07
影响因子：
15
通讯作者：
R. Altschul
中科院分区：
文献类型：
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作者：
R. Altschul
（3）本出版物中的定量测量是对更大系列的酯进行的，以补充原始探索性数据。本研究具有动力学通常所服务的双重目标：其结果允许对反应机理进行更准确的解释，并且它们以揭示某些情况下的刚性规律的方式提供了对结构和反应性的一般问题的额外见解，同时促进了对所有情况的至少半定量预测。在下面的提纲中，我们将首先把实验结果制成表格，然后讨论它们对结构和反应性之间关系的意义，沿着一些关于基元反应步骤的结论。结果
kjk,(3) The quantitative measurements in this present publication have been carried out on a larger series of esters to supplement the original exploratory data. This study has the dual objective com-monly served by kinetics: its results permit a more accurate interpretation of the reaction mech-anism, and they afford additional insight into the general problem of structure and reactivity in a manner to reveal a rigid law for some cases while facilitating at least semiquantitative predictions for all. In the outline below the experimental results will be tabulated first; their significance to therelationship between structure and reactiv-ity will be discussed next, along with some conclu-sions about the elementary reaction steps. Results