Nickel-catalysed cross-coupling reaction of aryl(trialkyl)silanes with aryl chlorides and tosylates.
Nickel-catalysed cross-coupling reaction of aryl(trialkyl)silanes with aryl chlorides and tosylates.
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DOI：
10.1039/c0cc02173c
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发表时间：
2011-01
影响因子：
4.9
通讯作者：
Shi Tang;Masahide Takeda;Y. Nakao;T. Hiyama
中科院分区：
文献类型：
--
作者：
Shi Tang;Masahide Takeda;Y. Nakao;T. Hiyama
使用高度稳定的，容易获得的，和可回收的2-（2-羟基丙-2-基）环己基取代的芳基硅烷活化的温和的碳酸盐碱，镍催化的硅基芳基-芳基交叉偶联反应进行第一次与廉价的芳基氯化物和甲苯磺酸酯在一个高度化学选择性的方式。
Using highly stable, readily accessible, and recyclable 2-(2-hydroxyprop-2-yl)cyclohexyl-substituted arylsilanes activated by a mild carbonate base, nickel-catalysed silicon-based aryl-aryl cross-coupling reaction proceeds for the first time with inexpensive aryl chlorides and tosylates in a highly chemoselective manner.