Synthesis of silver nanodisks using polystyrene mesospheres as templates

Synthesis of silver nanodisks using polystyrene mesospheres as templates
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DOI:
10.1021/ja028336r
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发表时间:
2002-12-25
影响因子:
15
通讯作者:
Schatz, GC
Schatz, GC
中科院分区:
化学1区
文献类型:
--
作者:
Hao, EC;Kelly, KL;Schatz, GC

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我们报道了以聚苯乙烯介观微球为模板合成银纳米盘。TEM测量表明,平均圆盘厚度为9.0 ± 1.0 nm,直径为36 ± 8 nm。这些粒子显示出强烈的电子光谱,与球体(紫色与黄色溶液)明显不同。我们目前的电磁理论计算表现出与所观察到的光谱的定性匹配,使我们能够分配几个等离子体共振功能。
We report the synthesis of Ag nanodisk using polystyrene mesospheres as templates. TEM measurements show that the average disk thickness is 9.0 ± 1.0 nm and the diameter is 36 ± 8 nm. The particles exhibit an intense electronic spectrum that differs markedly from that for spheres (purple vs yellow solutions). We present electromagnetic theory calculations which exhibit a qualitative match with the observed spectrum, enabling us to assign several of the plasmon resonance features.