TOTAL SYNTHESIS OF (+)-7-EPI-TARCHONANTHUSLACTONE VIA A CHELATIONCONTROLLED MUKAIYAMA ALDOL REACTION
TOTAL SYNTHESIS OF (+)-7-EPI-TARCHONANTHUSLACTONE VIA A CHELATIONCONTROLLED MUKAIYAMA ALDOL REACTION
复制标题
通过螯合控制的 Mukaiyama 羟醛反应全合成 ( )-7-EPI-塔克花内酯
DOI：
10.1080/00397911.2015.1014498
复制
发表时间：
2015
影响因子：
2.1
通讯作者：
Wang Xiaoji
中科院分区：
文献类型：
--
作者：
Huang Shuangping;Liu Dongwang;Tang Linjun;Huang Fei Fei;Zhang Jianting;Wang Xiaoji
An asymmetric total synthesis of (+)-7-epi-tarchonanthuslactone was achieved from commercially available methyl (R)-3-hydroxybutyrate. The key step employed a diastereoselective chelation-controlled Mukaiyama aldol reaction to construct the chiral hydroxyl group at the C-5 position.
