Sensitive and selective detection of L-tryptophan using Mn–ZnS QDs as the ratiometric emission probe

Sensitive and selective detection of L-tryptophan using Mn–ZnS QDs as the ratiometric emission probe
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DOI:
10.1039/c4ay00003j
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发表时间:
2014-04
期刊:
影响因子:
3.1
通讯作者:
Yanli Wei;Hongye Hao;Jiangang Zhang;X. Hao;C. Dong
Yanli Wei;Hongye Hao;Jiangang Zhang;X. Hao;C. Dong
中科院分区:
化学3区
文献类型:
--
作者:
Yanli Wei;Hongye Hao;Jiangang Zhang;X. Hao;C. Dong

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建立了一种基于单6-巯基-β-环糊精修饰的Mn掺杂ZnS量子点的比率荧光检测L-色氨酸的方法。相对于其他氨基酸,它对L-色氨酸表现出高度选择性的比率发射响应(400/598 nm)。将β-环糊精包被在Mn-ZnS量子点表面后,仍保留了分子识别能力,这也是确定L-色氨酸的原因。
A ratiometric fluorescence method for the detection of L-tryptophan based on mono-6-SH-β-cyclodextrin modified Mn-doped ZnS quantum dots has been developed. It exhibits a highly selective ratiometric emission response (400/598 nm) to L-tryptophan over other amino acids. β-Cyclodextrin still retained the ability of molecular recognition when it was coated on the surface of Mn–ZnS QDs, and this is also the cause for the identification of L-tryptophan.