A parahydrogen based NMR study of Pt catalysed alkyne hydrogenation
A parahydrogen based NMR study of Pt catalysed alkyne hydrogenation
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DOI：
10.1039/b925196k
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发表时间：
2010-01-01
影响因子：
4
通讯作者：
Lopez-Serrano, Joaquin
中科院分区：
文献类型：
--
作者：
Boutain, Marie;Duckett, Simon B.;Lopez-Serrano, Joaquin
基于仲氢的核磁共振研究的铂（II）双膦三氟甲磺酸酯催化氢化的炔在甲醇中揭示，铂双膦烷基阳离子和甲醇官能化的铂双膦烷基醚阳离子，是负责观察到的烯烃和乙烯基醚产品。
A parahydrogen based NMR study of the platinum(II) bis-phosphine triflate catalysed hydrogenation of alkynes in methanol reveals that platinum bis-phosphine alkyl cations and methanol functionalised platinum bis-phosphine alkylether cations, are responsible for the observed alkene and vinylether products.