Formation of Nanoporous Platinum by Selective Anodic Dissolution of PtZn Surface Alloy in a Lewis Acidic Zinc Chloride-1-Ethyl-3-methylimidazolium Chloride Ionic Liquid

Formation of Nanoporous Platinum by Selective Anodic Dissolution of PtZn Surface Alloy in a Lewis Acidic Zinc Chloride-1-Ethyl-3-methylimidazolium Chloride Ionic Liquid
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DOI:
10.1021/cm030462m
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发表时间:
2004-04
影响因子:
8.6
通讯作者:
Jing-Fang Huang;I. Sun
Jing-Fang Huang;I. Sun
中科院分区:
材料科学2区
文献类型:
--
作者:
Jing-Fang Huang;I. Sun

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采用一种简单的电化学方法,在刘易斯酸性ZnCl 2 -1-乙基-3-甲基咪唑氯化物离子液体中,通过PtZn的合金化和去合金化制备了高比表面积纳米结构铂电极。由于表面积增加,所得Pt电极显示出显著增强的氢和甲醇氧化还原反应电流。
A simple electrochemical strategy is described to prepare high surface area nanostructured platinum electrode by alloying and de-alloying of PtZn in a Lewis acidic ZnCl2-1-ethyl-3-methylimidazolium chloride ionic liquid. The resulting Pt electrode showed significantly enhanced current for hydrogen and methanol redox reactions, due to the increased surface area.