Symmetry rules for the differential Raman scattering of circularly polarized light by optically active molecules
Symmetry rules for the differential Raman scattering of circularly polarized light by optically active molecules
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DOI：
10.1039/j19710002899
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发表时间：
1971
期刊：
影响因子：
--
通讯作者：
L. Barron
中科院分区：
文献类型：
--
作者：
L. Barron
各种旋光性理论应用于旋光性分子对圆偏振光的微分拉曼散射。特别是，“单电子”理论提供了简单的对称规则，使得在拉曼光谱中具有明确定义的“指纹”的官能团的不对称环境能够被探测，这可以产生比不对称扰动发色团的o.r.d.和c.d.带更详细的构象和结构信息。
The various theories of optical activity are applied to the differential Raman scattering of circularly polarized light by optically active molecules. In particular, the ‘one electron’ theory provides simple symmetry rules which enable the dissymmetric environments of functional groups with well-defined ‘fingerprints’ in the Raman spectrum to be probed, and this could yield more detailed conformational and structural information than the o.r.d. and c.d. bands of dissymmetrically perturbed chromophores.