Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization.
Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization.
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DOI：
10.1002/ejoc.201403385
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发表时间：
2015-01
影响因子：
2.8
通讯作者：
Wijayantha KG
中科院分区：
文献类型：
--
作者：
Buckley BR;Patel AP;Wijayantha KG
二氧化碳的利用（CDU）目前正获得越来越多的兴趣，因为二氧化碳的丰度及其作为C1构建块的可能应用。我们在此报告了大气压下二氧化碳加入到氧乙烷中选择性地形成碳酸三亚甲基（TMC）的第一个例子，这是一个重大的挑战，因为TMC在热力学上不如其相应的共聚物有利。
Carbon dioxide utilisation (CDU) is currently gaining increased interest due to the abundance of CO2 and its possible application as a C1 building block. We herein report the first example of atmospheric pressure carbon dioxide incorporation into oxetane to selectively form trimethylene carbonate (TMC), which is a significant challenge as TMC is thermodynamically less favoured than its corresponding co-polymer.