The Synthesis and X-ray Structural Characterization of mer and fac isomers of the Technetium(I) Nitrosyl Complex [TcCl(2)(NO)(PNPpr)].
The Synthesis and X-ray Structural Characterization of mer and fac isomers of the Technetium(I) Nitrosyl Complex [TcCl(2)(NO)(PNPpr)].
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MER和FAC异构体的合成和X射线结构表征（I）硝基酶复合物[TCCL（2）（NO）（no）（pNPPR）]。
DOI：
10.1016/j.ica.2009.04.017
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发表时间：
2009-08-01
影响因子：
2.8
通讯作者：
Jones AG
中科院分区：
文献类型：
--
作者：
Nicholson TL;Mahmood A;Refosco F;Tisato F;Müller P;Jones AG
The nitrosyl complex H[TcNOCl4] reacts with the tridentate ligand bis[(2-diphenylphosphino)propyl]amine (PNPpr) to yield a mixture of the mer or fac isomers of [TcCl2(NO)(PNPpr)]. In acetonitrile, where the ligand is freely soluble, reaction occurs at room temperature to yield mostly the mer isomer with the linear nitrosyl ligand cis to the amine ligand; and the phosphine ligands arranged in a mutually trans orientation. The reaction in methanol requires reflux to dissolve the lipophilic ligand and generates the fac isomer of [TcCl2(NO)(PNPpr)] as the major product, with the tridentate ligand in a facial arrangement, leaving the chlorides and nitrosyl ligand in the remaining facial sites. The steric bulk of the tridentate ligand's diphenylphophino- moieties results in a significant distortion from octahedral geometry, with the P-Tc-P bond angle expanded to 99.48(4)°. The infrared spectra display absorptions from these nitrosyl ligands in the 1700 and 1800 cm−1 regions for the fac and mer isomers respectively. The ESI(+) mass spectra each display the parent ion at 647 m/z.
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DOI：
10.1107/s0108270187090528
发表时间：
1987-09-15
期刊：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
影响因子：
--
作者：
BROWN, DS;NEWMAN, JL;DAVISON, A
通讯作者：
DAVISON, A
影响因子：
2.8
作者：
Blanchard, SS;Nicholson, T;Jones, AG
通讯作者：
Jones, AG
影响因子：
4.6
作者：
Porchia, M;Tisato, F;Dolmella, A
通讯作者：
Dolmella, A
影响因子：
4.6
作者：
DAVISON, A;ORVIG, C;JONES, AG
通讯作者：
JONES, AG
影响因子：
2.8
作者：
Blanchard, SS;Nicholson, T;Jones, AG
通讯作者：
Jones, AG