Potentiometric discrimination of organic amines by a liquid membrane electrode based on a lipophilic hexaester of calix[6]arene
Potentiometric discrimination of organic amines by a liquid membrane electrode based on a lipophilic hexaester of calix[6]arene
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DOI：
10.1021/ac00056a022
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发表时间：
1993-04
影响因子：
7.4
通讯作者：
K. Odashima;K. Yagi;K. Tohda;Y. Umezawa
中科院分区：
文献类型：
--
作者：
K. Odashima;K. Yagi;K. Tohda;Y. Umezawa
研制了一种新型的聚氯乙烯基液膜电极，该电极能在中性pH下识别有机胺的非极性部分的空间形状。合成了一种新的杯[6]芳烃六酯[37，38，39，41，42-六（癸氧羰基甲氧基）杯[6]芳烃]，并将其作为一种传感元件
A novel type of poly(vinyl chloride) matrix liquid membrane electrode that is capable of discriminating the steric shapes of nonpolar that is capable of discriminating the steric shapes of nonpolar moities of organic amines at neutral pH has been developed. A new lipophilic hexaester of calix[6]arene having a well-defined inclusion cavity for organic guests [37,38,39,41,42-hexakis(decycloxycarbonylmethyloxy)calix[6]-arene] was synthesized and exploited as a sensory element