The Benthic B/Ca Record at Site 806: New Constraints on the Temperature of the West Pacific Warm Pool and the “El Padre” State in the Pliocene

The Benthic B/Ca Record at Site 806: New Constraints on the Temperature of the West Pacific Warm Pool and the “El Padre” State in the Pliocene
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DOI:
10.1029/2019pa003812
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发表时间:
2020-09
影响因子:
3.5
通讯作者:
S. White;A. Ravelo
S. White;A. Ravelo
中科院分区:
地球科学2区
文献类型:
--
作者:
S. White;A. Ravelo

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西太平洋暖池(WPWP)在上新世期间对pCO2增加的响应是一个关键的模型验证目标。不同的温度指标显示了不同的趋势:有孔虫的Mg/Ca海表温度(SST)记录显示上新世的WPWP温度比今天低1.2℃(Wara等,2005,https://doi.org/10.1126/science.1112596),而TEX86研究发现了降温趋势,并声称上新世的WPWP温度比今天高(Zhang等,2014,https://doi.org/10.1126/science.1246172)。我们将重点放在理解Mg/Ca数据的偏差作为约束上新世WPWP温度的最佳方法上。对有孔虫Mg/Ca的非热控制作用最强的是海水和溶蚀。溶解作用对Mg/Ca温度有较低的偏倚,这取决于Δ[CO32−],即方解石饱和所需的碳酸盐离子浓度的差值。因此,上新世代用物的差异可能源于Δ[CO32−]随时间的变化。为了限制溶解变化对Mg/Ca数据的影响,我们收集了0-5.5 Ma的WPWP中底栖有孔虫B/Ca数据(Δ[CO32−]的代理)。我们没有发现Δ[CO32−]的长期趋势,但在上新世中期至早期平均时,有孔虫溶解阈值以上和以下的变化产生了~0.4°C的冷偏。海水Mg/Ca的变化在上新世Mg/Ca资料中造成了~0.6°C的冷偏。在考虑这些偏差后,我们发现上新世的WPWP比全新世晚期低~0.1°C,范围在- 0.5°C到+0.5°C之间,包括所有不确定性。我们的重建显示,上新世热带太平洋的东西温度梯度比今天低得多,支持永久的El Niño - like“El Padre”状态。
The West Pacific Warm Pool (WPWP)'s response to increased pCO2 during the Pliocene is a key model validation target. Different temperature proxies show different trends: The foraminiferal Mg/Ca sea surface temperature (SST) record shows Pliocene WPWP temperatures ~1.2°C cooler than today (Wara et al., 2005, https://doi.org/10.1126/science.1112596), whereas a TEX86 study finds a cooling trend and claims the Pliocene WPWP was warmer than today (Zhang et al., 2014, https://doi.org/10.1126/science.1246172). We focus on understanding biases in Mg/Ca data as the best way to constrain the temperature of the Pliocene WPWP. The strongest nonthermal controls on foraminiferal Mg/Ca are Mg/Ca of seawater and dissolution. Dissolution, which imparts a cool bias to Mg/Ca temperatures, depends on Δ[CO32−], the difference from the carbonate ion concentration needed for calcite saturation. Thus, Pliocene proxy discrepancies might stem from varying Δ[CO32−] over time. To constrain the effect of changing dissolution on the Mg/Ca data, we collected benthic foraminiferal B/Ca data (a proxy for Δ[CO32−]) from the WPWP spanning 0–5.5 Ma. We find no long‐term trend in Δ[CO32−], but variations above and below the threshold of foraminiferal dissolution yield an ~0.4°C cold bias when averaged over the middle to early Pliocene. Changes in seawater Mg/Ca create an ~0.6°C cold bias in the Pliocene Mg/Ca data. After accounting for these biases, we find that the Pliocene WPWP was ~0.1°C cooler than the late Holocene, ranging from −0.5°C to +0.5°C including all uncertainties. Our reconstruction shows a much lower east‐west temperature gradient in the Pliocene tropical Pacific than today, supporting a permanent El Niño‐like “El Padre” state.