The layered metal Ti2PTe2

The layered metal Ti2PTe2
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层状金属Ti2PTe2

DOI:
10.1016/j.jssc.2008.07.018
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发表时间:
2008
影响因子:
3.3
通讯作者:
A. Isaeva
A. Isaeva
中科院分区:
化学3区
文献类型:
--
作者:
F. Philipp;P. Schmidt;M. Ruck;W. Schnelle;A. Isaeva

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A new V(III) lithium phosphate Li{sub 5}VO(PO{sub 4}){sub 2} has been synthesized by electrochemical insertion of lithium into Li{sub 4}VO(PO{sub 4}){sub 2}. This phase, which crystallizes in the space group I4/mcm, exhibits a tunnel structure closely related to the layered structure of Li{sub 4}VO(PO{sub 4}){sub 2} and to the tunnel structure of VO(H{sub 2}PO{sub 4}){sub 2}. The topotactic reactions that take place during lithium exchange and intercalation, starting from VO(H{sub 2}PO{sub 4}){sub 2} and going to the final phase Li{sub 5}VO(PO{sub 4}){sub 2} are explained on the basis of the flexible coordinations of V{sup 4+} and V{sup 3+} species. The electrochemical and magnetic properties of this new phase are also presented and explained on the basis of the structure dimensionality. - Graphical abstract: Electrochemical synthesis of a new 3D V(III) lithium phosphate, Li{sub 5}VO(PO{sub 4}){sub 2}. Starting from the 2D Li{sub 4}VO(PO{sub 4}){sub 2}, the topotactic reaction that take place during lithium intercalation is explained on the basis of the flexible coordinations of V{sup 4+} and V{sup 3+} species.
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