Resolution of monoterpene enantiomers by gas chromatography.
Resolution of monoterpene enantiomers by gas chromatography.
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通过气相色谱法拆分单萜对映体。
DOI：
10.1016/s0021-9673(01)92622-6
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发表时间：
1987
期刊：
影响因子：
--
通讯作者：
Croteau,RB
中科院分区：
文献类型：
--
作者：
Satterwhite,DM;Croteau,RB
对映体单萜可通过气相色谱法在常规毛细管柱和填充柱上拆分，然后转化为（2 R，3R）-2，3-丁二醇的非对映体缩酮。描述了用于衍生化和分离亚毫克量的α-蒎烯、β-蒎烯、异松油烯、桧烯、α-崖柏烯、柠檬烯和3-$>烯的对映体以及结构上相关的醇和酮的有效方法。
Enantiomeric monoterpenes can be resolved by gas chromatography on conventional capillary and packed columns following conversion to diastereomeric ketals of (2R, 3R)-2, 3-butanediol. Efficient methods are described for the derivatization and separation of sub-milligram quantities of the enantiomers of alpha-pinene, beta-pinene, camphene, sabinene, alpha-thujene, limonene and 3-carene, as well as of structurally related alcohols and ketones.