Stepwise synthesis and properties of a 9,10-dihydro-9,10-diboraanthracene
Stepwise synthesis and properties of a 9,10-dihydro-9,10-diboraanthracene
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DOI：
10.1016/j.tetlet.2010.07.068
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发表时间：
2010-09-22
影响因子：
1.8
通讯作者：
Kawashima, Takayuki
中科院分区：
文献类型：
--
作者：
Agou, Tomohiro;Sekine, Masaki;Kawashima, Takayuki
建立了一种9，10-二氢-9，10-二硼杂菲的分步合成方法，并对其光学和电化学性质以及分子结构进行了研究。9，10-二氢-9，10-二硼杂菲对氟离子具有很强的络合能力，并伴随着光致发光的增强，这可能是由于两个硼原子之间的分子内电荷转移所致。(C)2010爱思唯尔有限公司。保留所有权利。
A stepwise synthetic method for a 9,10-dihydro-9,10-diboraanthracene was developed, and the optical and electrochemical properties as well as the molecular structure of the 9,10-dihydro-9,10-diboraanthracene were elucidated. The 9,10-dihydro-9,10-diboraanthracene exhibited high complexation ability against fluoride ion, and the complexation was accompanied by the enhancement of photoluminescence emission, probably due to intramolecular charge transfer between the two boron atoms. (C) 2010 Elsevier Ltd. All rights reserved.