Supramolecular bidentate phosphine ligand scaffolds from deconstructed Hamilton receptors
Supramolecular bidentate phosphine ligand scaffolds from deconstructed Hamilton receptors
复制标题
来自解构的汉密尔顿受体的超分子二齿膦配体支架
DOI：
10.1039/c6cc09198a
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发表时间：
2017
影响因子：
4.9
通讯作者：
Pluth, Michael D.
中科院分区：
文献类型：
--
作者：
Seidenkranz, Daniel T.;McGrath, Jacqueline M.;Zakharov, Lev N.;Pluth, Michael D.
对可以利用无机和有机金属结构的新配体结构的需求不断增加。一类重要但通常具有合成挑战性的配体是二齿膦。在这里，我们报告了基于解构的汉密尔顿受体的自组装超分子二齿配体支架，其结合亲和力高达 800 ± 100 M−1。
There is constant demand for new ligand archictectures on which inorganic and organometallic structures can be leveraged. An important, but often synthetically challenging, class of ligands is bidentate phosphines. Here we report self-assembling, supramolecular bidentate ligand scaffolds based on deconstructed Hamilton receptors with binding affinities up to 800 ± 100 M−1.