Polaron stability in semiconducting polymer neat films
Polaron stability in semiconducting polymer neat films
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DOI：
10.1039/c4cc06193d
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发表时间：
2014-01-01
影响因子：
4.9
通讯作者：
Durrant, James R.
中科院分区：
文献类型：
--
作者：
Beatrup, Daniel;Wade, Jessica;Durrant, James R.
我们描述了一种光谱电化学方法，以加速氧化应激下的共轭聚合物的电化学稳定性研究。基于（i）噻吩和噻唑，即PTTz，和（ii）联噻吩和噻唑，即PTTTz的交替共聚物的极化子稳定性在纯膜中与P3HT的极化子稳定性进行比较。发现P3HT最稳定，而PTTz最不稳定。
We describe a spectroelectrochemical approach to accelerated electrochemical stability studies of conjugated polymers under oxidative stress. The polaron stabilities of alternating copolymers based on (i) thiophene and thiazole, namely PTTz, and (ii) bithiophene and thiazole, namely PTTTz, are compared in neat films with that of P3HT. P3HT is found to be the most stable whilst PTTz is found to be the least stable.