The first ligand-modulated oxidative Heck vinylation. Efficient catalysis with molecular oxygen as palladium(0) oxidant

The first ligand-modulated oxidative Heck vinylation. Efficient catalysis with molecular oxygen as palladium(0) oxidant
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DOI:
10.1039/b311492a
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发表时间:
2004-01-21
影响因子:
4.9
通讯作者:
Larhed, M
Larhed, M
中科院分区:
化学2区
文献类型:
--
作者:
Andappan, MMS;Nilsson, P;Larhed, M

文献摘要

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首次发现了以分子氧为复氧剂的Pd(II)催化氧化Heck反应,并报道了仅用1-2%的催化剂即可与多种芳基硼酸和烯烃反应的范围。
The discovery of the first ligand-supported Pd(II) catalysed oxidative Heck reaction with molecular oxygen as reoxidant and the scope with diverse arylboronic acids and olefins using only 1-2% of catalyst are reported.