Hierarchically assembled ZnO nanocrystallites for high-efficiency dye-sensitized solar cells.

Hierarchically assembled ZnO nanocrystallites for high-efficiency dye-sensitized solar cells.
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DOI:
10.1002/anie.201104605
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发表时间:
2011-12
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通讯作者:
N. Memarian;I. Concina;A. Braga;S. M. Rozati;A. Vomiero;G. Sberveglieri
N. Memarian;I. Concina;A. Braga;S. M. Rozati;A. Vomiero;G. Sberveglieri
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作者:
N. Memarian;I. Concina;A. Braga;S. M. Rozati;A. Vomiero;G. Sberveglieri

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在能量转换效率和长期稳定性方面表现出最高的性能,尽管由于电荷传输的固有限制,效率保持在13%以下。光电极的结构是决定光电化学系统功能性质的关键。特别是,光阳极由具有高比表面积(通常是体相对应物的一千倍)的中孔宽带隙氧化物半导体膜组成。
exhibit the highest performance interms of energy conversion efficiency and long term stability,despite the fact that the efficiency remains below 13%because of the intrinsic limitation in charge transport. Thestructure of the photoelectrodes is crucial in determining thefunctional properties of the photoelectrochemical system. Inparticular, the photoanode consists of a mesoporous wide-band-gap oxide semiconductor film with a high specificsurface (typically a thousand times larger than the bulkcounterpart).