Aprotic Lithium‐Carbon Dioxide Batteries: Reaction Mechanism and Catalyst Design
Aprotic Lithium‐Carbon Dioxide Batteries: Reaction Mechanism and Catalyst Design
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DOI：
10.1002/tcr.202200109
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发表时间：
2022-07
期刊：
影响因子：
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通讯作者：
Yunyun Xu;Yujiao Xia;Hairong Xue;Hao Gong;Kun Chang;Jianping He;Tao Wang-;R. Ma
中科院分区：
文献类型：
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作者：
Yunyun Xu;Yujiao Xia;Hairong Xue;Hao Gong;Kun Chang;Jianping He;Tao Wang-;R. Ma
近年来，化石燃料的燃烧导致大量CO2气体的释放，引发了温室效应和能源危机。为了解决这些问题，研究人员将注意力转向了新型Li-CO2电池（LCB）。LCB由于其高的理论能量密度和可逆的CO2还原/析出过程而受到广泛关注。到目前为止，新兴的LCB仍然面临着来自放电产物的缓慢反应动力学的许多挑战。本文系统地阐述了LCB的最新研究现状和进展，特别是阴极催化剂的结构设计对电池性能的影响。本文详细总结了锂离子电池存在的问题及可能的解决方案，对进一步推动锂空气电池的发展具有较高的研究价值。
In recent years, the combustion of fossil fuels leads to the release of a large amount of CO2 gas, which induces the greenhouse effect and the energy crisis. To solve these problems, researchers have turned their focus to a novel Li‐CO2 battery (LCB). LCB has received much attention because of its high theoretical energy density and reversible CO2 reduction/evolution process. So far, the emerging LCB still faces many challenges derived from the slow reaction kinetics of discharge products. In this review, the latest status and progress of LCB, especially the influence of the structure design of cathode catalysts on the battery performance, are systematically elaborated. This review summarizes in detail the existing issues and possible solutions of LCB, which is of high research value for further promoting the development of Li‐Air battery.