Organocatalytic asymmetric direct alkylation of α-diazoester via C-H bond cleavage
Organocatalytic asymmetric direct alkylation of α-diazoester via C-H bond cleavage
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DOI:
10.1021/ja051922a
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发表时间:
2005-07-06
影响因子:
15
通讯作者:
Terada, M
中科院分区:
文献类型:
--
作者:
Uraguchi, D;Sorimachi, K;Terada, M
A new variant of phosphoric acid-catalyzed C−C bond forming reaction, direct alkylation of α-diazoester, via C−H bond cleavage is presented. The resulting products, β-amino-α-diazoesters, are highly functionalized and useful synthetic precursors for various types of β-amino acids.