Chemical engineering of the single-walled carbon nanotube-nylon 6 interface
Chemical engineering of the single-walled carbon nanotube-nylon 6 interface
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DOI：
10.1021/ja057484p
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发表时间：
2006-06-14
影响因子：
15
通讯作者：
Haddon, RC
中科院分区：
文献类型：
--
作者：
Gao, JB;Zhao, B;Haddon, RC
We report an approach to the chemical engineering of the single-walled carbon nanotube ( SWNT)-polymer interfacial interaction in a nylon 6 graft copolymer composite which is based on the degree of SWNT functionality. Continuous fibers are drawn from composites fabricated from the in situ polymerization of caprolactam with SWNTs possessing a range of carboxylic acid ( SWNT-COOH) and amide ( SWNT-CONH2) functionalities. Mechanical performance evaluation of the composite fibers shows that a high concentration of the carboxylic acid functional groups leads to a stronger SWNT-nylon interfacial interaction, as reflected in greater values of the Young's modulus and mechanical strength. Replacement of the COOH group by CONH2 in the SWNT starting material changes the grafting polymerization chemistry, thereby leading to the covalent attachment of longer graft copolymer chains to the SWNTs, and alters the composite morphology while increasing the composite flexibility and toughness.
