A stereodivergent approach to chiral nonracemic n-protected α, α-dialkylated amino acids
A stereodivergent approach to chiral nonracemic n-protected α, α-dialkylated amino acids
复制标题
手性非外消旋 n-保护 α, α-二烷基化氨基酸的立体发散方法
DOI：
10.1021/ja037078a
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发表时间：
2003
影响因子：
15
通讯作者：
Cedrickx Gobdout
中科院分区：
文献类型：
--
作者：
C. Spino;Cedrickx Gobdout
Menthyl carboxaldehyde is used as a chiral auxiliary to make quaternary amino acids of either configuration via a stereodivergent approach that includes an SN2‘ displacement by a cuprate reagent and a Curtius rearrangement as key steps.
