THE REDUCTION OF SILVER VANADIUM-OXIDE IN LITHIUM SILVER VANADIUM-OXIDE CELLS
THE REDUCTION OF SILVER VANADIUM-OXIDE IN LITHIUM SILVER VANADIUM-OXIDE CELLS
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DOI：
10.1149/1.2095412
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发表时间：
1988-11-01
影响因子：
3.9
通讯作者：
THIEBOLT, WC
中科院分区：
文献类型：
--
作者：
TAKEUCHI, ES;THIEBOLT, WC
结论我们的研究表明，BrC 1在Li/SOC 12电池中的存在显着修改电池的放电化学。电池中BrCl的放电通过C12、Br 2和BrCl的还原进行。BrCl的存在有助于除去一些由SOCl 2还原形成的S。然而，它也会在部分放电的电池中产生硫卤化物、SO2 Br 2和Br 2，这似乎会对部分放电后电池的可储存性产生不利影响。
ConclusionsOur studies indicate that the presence of BrC1 in a Li/SOC12 cell significantly modifies the discharge chemistry of the cell. The discharge of the BrC1 in the cell proceeds through the reductions of C12, Br2, and BrC1. The presence of BrC1 helps to remove some of the S formed by the reduction of SOC12. However, it also produces sulfur halides, SO2Br2, and Br2 in partially discharged cells, which appears to adversely affect the storability of the cell after partial discharge.