Silicon based lithium-ion battery anodes: A chronicle perspective review
Silicon based lithium-ion battery anodes: A chronicle perspective review
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DOI：
10.1016/j.nanoen.2016.11.013
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发表时间：
2017
期刊：
影响因子：
17.6
通讯作者：
Xiuxia Zuo;Jin Zhu;P. Müller‐Buschbaum;Yajun Cheng
中科院分区：
文献类型：
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作者：
Xiuxia Zuo;Jin Zhu;P. Müller‐Buschbaum;Yajun Cheng
硅材料因其优异的容量和合适的工作电压而被认为是最有前途的下一代锂离子电池负极材料之一。然而，在锂化/脱锂过程期间的显著体积变化已经引起严重的有害后果，导致非常差的循环稳定性。这一直是制约硅基锂离子电池阳极实用化的关键问题之一。自20世纪90年代初以来，为解决这一问题进行了广泛的研究。本文首次从历史的角度对近二十多年来硅阳极的研究进行了总结和讨论。通过本文，对硅锂离子电池阳极概念的演变、基础科学和技术的发展作了较为清晰的介绍。本文对这一快速发展的领域提供了独特的视角，并将对硅锂离子电池阳极的未来研究趋势有所启示。
Si has been regarded as one of the most promising next generation lithium-ion battery (LIB) anodes due to its exceptional capacity and proper working voltage. However, the dramatic volume change during lithiation/delithiation processes has caused severe detrimental consequences, leading to very poor cyclic stability. It has been one of the critical problems hampering the practical applications of the silicon based LIB anode. Extensive research has been carried out to resolve the problem since early 1990s. For the first time, the studies on the Si anode in the time frame more than two decades are summarized and discussed in this review with a novel chronicle perspective. Through this article, the evolution of the concept, fundamental scientific and technology development of the silicon LIB anode are clearly presented. It provides unique eyesight into this rapid developing field and will shed light on the future trend of the Si LIB anode research.