Observation of electroluminescence at room temperature from a ruthenium(II) bis-terpyridine complex and its use for preparing light-emitting electrochemical cells
Observation of electroluminescence at room temperature from a ruthenium(II) bis-terpyridine complex and its use for preparing light-emitting electrochemical cells
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DOI：
10.1021/ic0507058
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发表时间：
2005-08-22
影响因子：
4.6
通讯作者：
Gaviña, P
中科院分区：
文献类型：
--
作者：
Bolink, HJ;Cappelli, L;Gaviña, P
合成了一种含取代和未取代的联吡啶Ru(11)配合物，并在固态单层发光电化学池中对其发光性能进行了研究。所获得的器件在较低的外加偏压下发出了非常深的红色(CIE，x=0.717，y=0.282)的光。这是基于双螯合Ru络合物的电致发光器件的第一个例子。它的环境大气衰减与使用三螯合Ru络合物的类似装置有很大不同。
A terpyridine ruthenium (11) complex containing a substituted and an unsubstituted terpyridine ligand was synthesized, and its luminescence properties were studied in a solid-state single-layer light-emitting electrochemical cell. The obtained devices emitted light of a very deep red color (CIE, x = 0.717 y = 0.282) at low external applied bias. It is the first example of an electroluminescence device based on a bis-chelated ruthenium complex. Its ambient atmosphere decay is remarkably different from analogous devices using tris-chelated ruthenium complexes.