Multi-chiro-informative System Created by a Porphyrin-functionalized Chiral Molecular Assembly
Multi-chiro-informative System Created by a Porphyrin-functionalized Chiral Molecular Assembly
复制标题
由卟啉功能化手性分子组装形成的多手性信息系统
DOI：
10.1246/cl.200018
复制
发表时间：
2020-04-01
影响因子：
1.6
通讯作者：
Ihara, Hirotaka
中科院分区：
文献类型：
--
作者：
Mashima, Sayaka;Ryu, Naoya;Ihara, Hirotaka
我们引入了多手性光学活性有机系统，通过非手性卟啉部分的手性分子取向表现出圆二色性、荧光和圆偏振发光。这些独特系统的光谱对外部条件（包括对映体因子）明显敏感。
We introduce multi-chiroptically active organic systems that exhibit circular dichroism, fluorescence and circularly polarized luminescence through chiral molecular orientation of a non-chiral porphyrin moiety. The spectra of these unique systems are distinctly sensitive to external conditions, including an enantiomeric factor.