SPECIFICATION OF MOLECULAR CHIRALITY
SPECIFICATION OF MOLECULAR CHIRALITY
复制标题
DOI：
10.1002/anie.196603851
复制
发表时间：
1966-01-01
影响因子：
16.6
通讯作者：
PRELOG, V
中科院分区：
文献类型：
--
作者：
CAHN, RS;INGOLD, C;PRELOG, V
手性分子模型的拓扑分析为手性的描述提供了一般体系的框架。在1956年及以前，这个体系对有机化学构型的应用一般被保留下来，但对某些类型的结构进行了重新定义，主要是根据1956年以来贝尔斯坦研究所和其他地方获得的经验。该系统现在扩展到处理，一方面，与有机化学构象，另一方面，与无机化学构型配体6。考虑了与手性规格从型号到名称的转换有关的问题，特别是一般系统和限定范围系统的表达命名中的共生关系。
The topological analysis of chiral molecular models has provided the framework of a general system for the specification of their chirality. The application, made in and before 1956, of this system to organic‐chemical configurations is generally retained, but is redefined with respect to certain types of structure, largely in the light of experience gained since 1956 in the Beilstein Institute and elsewhere. The system is now extended to deal, on the one hand, with organic‐chemical conformations, and, on the other, with inorganic‐chemical configurations to ligancy six. Matters arising in connexion with the transference of chiral specifications from model to name are considered, notably that of the symbiosis in nomenclature of expressions of the general system and of systems of confined scope.For corrigendum see DOI:10.1002/anie.196605111