Coordination-Insertion Copolymerization of Allyl Monomers with Ethylene
Coordination-Insertion Copolymerization of Allyl Monomers with Ethylene
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DOI：
10.1021/ja1092216
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发表时间：
2011-02-09
影响因子：
15
通讯作者：
Nozaki, Kyoko
中科院分区：
文献类型：
--
作者：
Ito, Shingo;Kanazawa, Masafumi;Nozaki, Kyoko
以钯/膦磺酸盐为催化剂，研究了烯丙基单体与乙烯的配位嵌入型共聚反应。各种烯丙基单体，包括乙酸烯丙酯、烯丙醇、保护的烯丙胺和烯丙基卤化物，与乙烯共聚，形成具有链上CH2CH(CH(2)FG)-基团的高度线性共聚物。
Coordination-insertion copolymerization of allyl monomers with ethylene was developed by using a palladium/phosphine-sulfonate catalyst. A variety of allyl monomers, including allyl acetate, allyl alcohol, protected allylamines, and allyl halides, were copolymerized with ethylene to form highly linear copolymers that possess in-chain -CH2CH(CH(2)FG)- units.