Re(VII) complex of N-fused tetraphenylporphyrin

Re(VII) complex of N-fused tetraphenylporphyrin
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DOI:
10.1039/b508208k
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发表时间:
2005-01-01
影响因子:
4.9
通讯作者:
Furuta, H
Furuta, H
中科院分区:
化学2区
文献类型:
--
作者:
Toganoh, M;Ikeda, S;Furuta, H

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用三甲胺n -氧化物处理n -熔融四苯基卟啉铼(I)三羰基配合物,金属中心氧化得到n -熔融四苯基卟啉铼(VII)三羰基配合物,该配合物对空气、光和热都很稳定。
By treatment of N-fused tetraphenylporphyrin rhenium( I) tricarbonyl complex with trimethylamine N-oxide, oxidation of the metal center proceeded to afford N-fused tetraphenylporphyrin rhenium(VII) trioxo complex, which was quite stable against air, light and heat.