L-Lysine derived organogelator-based chiral stationary phase for mixed-mode liquid chromatography
L-Lysine derived organogelator-based chiral stationary phase for mixed-mode liquid chromatography
复制标题
用于混合模式液相色谱的 L-赖氨酸衍生的基于有机凝胶剂的手性固定相
DOI：
10.1039/c5ay00405e
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发表时间：
2015
影响因子：
3.1
通讯作者：
H. Ihara
中科院分区：
文献类型：
--
作者：
S. Gurahain;A. K. Mallik;M. Takafuji;H. Ihara
一个L-赖氨酸基，脲含有机凝胶改性硅胶固定相，有序功能团，适用于手性分析物和极性分析物的分离。固定相中的分子取向的功能基团排列增强了色谱性能，从而使手性和极性分析物的分离成为可能。首次报道了利用凝胶剂-二氧化硅杂化粒子进行手性分离。
An L-lysine-based, urea containing organogelator-modified silica stationary phase, with ordered functional groups, was applied for the separation of chiral analytes and polar analytes. The molecularly oriented functional group arrangement in the stationary phase enhanced the chromatographic performance thus making the separation of chiral and polar analytes possible. Chiral separation using gelator–silica hybrid particles is reported for the first time.