High-spin behaviour and chemical properties of organometalic dervatives of iron(III)
High-spin behaviour and chemical properties of organometalic dervatives of iron(III)
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铁(III)有机金属衍生物的高自旋行为和化学性质
DOI：
10.1016/s0010-8545(00)80052-1
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发表时间：
1972
期刊：
影响因子：
--
通讯作者：
F. Calderazzo
中科院分区：
文献类型：
--
作者：
C. Floriani;F. Calderazzo
文献中报道了相对较少的铁（II1）有机金属化合物的例子。最近通过格氏反应器在具有异卟啉类型结构的铁（III）卤代衍生物上制备了铁碳α键。分离的化合物是对甲苯基和乙基衍生物，分别为深蓝色和紫色固体，对光敏感。据我们所知，除这些化合物外，还没有其他有关分离铁 (II1) 有机金属化合物的报道出现。
Relatrvely few examples of organometalhc compounds of rron (II1) have been reported m the literature Iron-carbon a-bonds have been prepared recently’by a Grrgnard reactron on rron (III)-halo derrvatrves with an etroporphyrm type of structure_ The compounds Isolated were the p-tolyl and the ethyl denvatrves as dark blue and purple sohds, respectrvely, sensrtrve to bght Besides these compounds, no other reports concernmg the isolation of iron (II1) organometalhc compounds have appeared, to the best of our knowledge The thermal mstabrlrty of compounds of thrs type was further suggested by the