DEUTERATED WATER EFFECTS ON ACID IONIZATION CONSTANTS

DEUTERATED WATER EFFECTS ON ACID IONIZATION CONSTANTS
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DOI:
10.1126/science.139.3560.1198
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发表时间:
1963-01-01
期刊:
影响因子:
56.9
通讯作者:
MARTIN, RB
MARTIN, RB
中科院分区:
综合性期刊1区
文献类型:
--
作者:
MARTIN, RB

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形式为 ΔpK=pKD-pKH=a+bpKH 的线性关系对于任何种类的酸,轻水和重水中酸的电离常数必须具有相同的斜率b,除非先前未考虑的电荷类型很重要或者该方程无效。
Linear relations of the form ΔpK=pKD-pKH=a+bpKHrelating ionization constants of acids in light and heavy water must have the same slopebfor any kind of acid unless the previously unconsidered charge type is important or this equation is not valid.