Polymeric Monosaccharide Receptors Responsive at Neutral pH
Polymeric Monosaccharide Receptors Responsive at Neutral pH
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DOI：
10.1021/ja905652w
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发表时间：
2009-10-07
影响因子：
15
通讯作者：
van Hest, Jan C. M.
中科院分区：
文献类型：
--
作者：
Kim, Kyoung Taek;Cornelissen, Jeroen J. L. M.;van Hest, Jan C. M.
本文首次详细报道了Wulff型苯乙烯类单体的合成及其自由基加成-断裂链转移（RAFT）聚合。所得聚合物和嵌段共聚物在单糖如D-果糖和D-葡萄糖存在下在水性缓冲溶液（pH = 7.4-7.8）中表现出糖响应性增溶。
We present the first detailed report of the synthesis of Wulff-type styrenic monomers and their polymerization by radical addition-fragmentation chain transfer (RAFT) methods. The resulting polymers and block copolymers exhibit sugar-responsive solubilization in aqueous buffer solutions (pH = 7.4-7.8) in the presence of monosaccharides such as D-fructose and D-glucose.