Photovoltaic cell characteristics of hybrid silicon devices with lanthanide complex phosphor-coating film
Photovoltaic cell characteristics of hybrid silicon devices with lanthanide complex phosphor-coating film
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DOI：
10.1149/1.1838135
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发表时间：
1997-11-01
影响因子：
3.9
通讯作者：
Adachi, G
中科院分区：
文献类型：
--
作者：
Jin, T;Inoue, S;Adachi, G
硅光伏电池的转换效率值显着提高，通过表面涂层的有机改性硅酸盐（ORMOSIL）复合荧光膜，将铕（III）菲咯啉和铽（III）联吡啶配合物。通过优化ORMOSIL复合膜的复合浓度，与未涂覆的c-Si和a-Si相比，涂覆的单晶（c-Si）和非晶硅（a-Si）光伏器件的相对最大输出分别提高到118%和108%。空气质量1.5（100 mW cm（-2）），这是由于通过掺入到ORMOSIL基质中的镧系元素络合物将太阳光的紫外部分有效地光学转换为可见光。
Conversion efficiency values of silicon photovoltaic cells were significantly enhanced, by surface coating of the organically modified silicate (ORMOSIL) composite phosphor films incorporating europium(III) phenanthroline and terbium(III) bipyridine complexes. Relative maximal outputs of the coated single-crystal (c-Si) and amorphous silicon (a-Si) photovoltaic devices compared with those of the uncoated c-Si and a-Si ones were increased to 118 and 108%, respectively, by optimizing for the complex concentration of the ORMOSIL composite films under air mass 1.5 (100 mW cm(-2)), owing to the effective optical conversion from the ultraviolet fraction of sunlight to visible lights by the lanthanide complexes incorporated into the ORMOSIL matrix.