Reactions and photochemistry of chromium and molybdenum with molecular hydrogen at 12 K
Reactions and photochemistry of chromium and molybdenum with molecular hydrogen at 12 K
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12 K 下铬和钼与氢分子的反应和光化学
DOI：
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发表时间：
1992
期刊：
影响因子：
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通讯作者：
J. Margrave
中科院分区：
文献类型：
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作者：
Z. Xiao;R. Hauge;J. Margrave
本文描述了12 K时Cr和Mo原子与Kr和Ar基体中氢分子的相互作用。在用UV光光解时，发现Cr和Mo都与H{sub 2}光反应，形成CrH{sub 2}、CrH{sub 3}和MoH{sub n}（n=1-4）。作者报告键角和拉伸模式常数的二氢化物分子。
Here the authors describe the interactions of Cr and Mo atoms with hydrogen molecules in Kr and Ar matrices at 12K. Upon photolysis with UV light both Cr and Mo are found to be photoreactive with H{sub 2}, forming CrH{sub 2}, CrH{sub 3}, and MoH{sub n} (n=1-4). The authors report bond angles and stretching mode constants for the dihydride molecules.