Design of functional nano-structured materials through the use of controlled hybrid organic–inorganic interfaces

Design of functional nano-structured materials through the use of controlled hybrid organic–inorganic interfaces
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DOI:
10.1016/j.crci.2003.06.001
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发表时间:
2003-08
影响因子:
1.6
通讯作者:
C. Sanchez;Galo J. A. A. Soler-Illia-Galo-J.-A.-A.-Soler-Illia-1398329617;F. Ribot;D. Grosso
C. Sanchez;Galo J. A. A. Soler-Illia-Galo-J.-A.-A.-Soler-Illia-1398329617;F. Ribot;D. Grosso
中科院分区:
化学4区
文献类型:
--
作者:
C. Sanchez;Galo J. A. A. Soler-Illia-Galo-J.-A.-A.-Soler-Illia-1398329617;F. Ribot;D. Grosso

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通过将溶胶-凝胶过程与无机或杂化网络的模板化生长相结合提供的化学策略,包括与表面活性剂中间相或有机凝胶的自组装,以及与外部请求的结合,使我们能够通过智能和可调的编码来开发具有复杂结构的创新材料。这些方法中,化学和过程是强耦合的,允许将大量的分子前体、低聚物、簇或纳米颗粒(纳米构建块)组装成功能分级结构。在这篇简短的综述文章中,通过我们研究组开发的几个引人注目的例子,说明了允许设计厚膜或薄膜、微粒和纤维形状的纳米结构和/或微结构无机材料和杂化材料的不同策略。引用本文:C.Sanchez等人,C.R.Chimie 6(2003)。
The chemical strategies offered by combining sol-gel processes together with the templated growth of inorganic or hybrid networks involving self-assembly with surfactant mesophases or organogels, and with external solicitations allows us, through an intelligent and tuned coding, to develop innovative materials having complex architectures. These methods where chemistry and process are strongly coupled, allow directing the assembling of a large variety of molecular precursors, oligomers, clusters or nanoparticles (nanobuilding blocks) into functional hierarchical structures. In this short review article, the different strategies allowing to design nanostructured and/or microtextured inorganic and hybrid materials shaped as thick or thin films, microparticles and fibres are illustrated with several striking examples developed in our research group. To cite this article: C. Sanchez et al., C. R. Chimie 6 (2003).