The Mercury (II) Catalyzed, One-Pot Oxidation of Terminal Alkynes by Sodium Perborate in Acetic Acid
The Mercury (II) Catalyzed, One-Pot Oxidation of Terminal Alkynes by Sodium Perborate in Acetic Acid
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DOI：
10.1080/00397918908052660
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发表时间：
1989-08
影响因子：
2.1
通讯作者：
K. L. Reed;J. Gupton;Karyn L. McFarlane
中科院分区：
文献类型：
--
作者：
K. L. Reed;J. Gupton;Karyn L. McFarlane
摘要以过硼酸钠和醋酸汞为催化剂，在乙酸中反应一系列末端炔，得到1-乙酰氧基烷-2-酮，收率高。该反应是一种温和、简便的氧化末端三键的方法。
Abstract A series of terminal alkynes has been reacted with sodium perborate and mercuric acetate catalyst in acetic acid to produce 1-acetoxyalkan-2-ones in good yield. The reaction constitutes a mild and convenient method for the oxidation of terminal triple bonds.