STRUCTURE ELUCIDATION OF A NOVEL TRICHOTHECENE GLYCOSIDE USING H-1 AND C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY
STRUCTURE ELUCIDATION OF A NOVEL TRICHOTHECENE GLYCOSIDE USING H-1 AND C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY
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DOI:
10.1039/p19850001553
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发表时间:
1985-01-01
期刊:
影响因子:
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通讯作者:
RABIE, CJ
中科院分区:
文献类型:
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作者:
GORSTALLMAN, CP;STEYN, PS;RABIE, CJ
The structure elucidation of a novel trichothecene glycoside, 15-acetoxy-3.alpha.-hydroxy-4.beta.-(.alpha.-D-glucopyranosyloxy)-12,13-epoxytrichothec-9-ene [from Fusarium sulfureum] is based on a detailed study of its one- and two-dimensional 1H and 13C n.m.r. spectra, and chemical reactions. The metabolite displays a reduced toxicity when compared with other trichothecane metabolites in several biological systems.