Iron-catalyzed selective biaryl coupling: Remarkable suppression of homocoupling by the fluoride anion
Iron-catalyzed selective biaryl coupling: Remarkable suppression of homocoupling by the fluoride anion
复制标题
DOI：
10.1021/ja073084l
复制
发表时间：
2007-08-15
影响因子：
15
通讯作者：
Nakamura, Masaharu
中科院分区：
文献类型：
--
作者：
Hatakeyama, Takuji;Nakamura, Masaharu
在氟化铁和1，3-二(2，6-二丙基苯基)咪唑氯化物存在下，芳基溴化镁与芳基氯化物反应生成相应的交叉偶联产物--不对称联芳基，产率很高。
In the presence of iron(III) fluoride and 1,3-bis(2,6-di-i-propylphenyl)imidazolinium chloride, aryl magnesium bromides react with aryl chlorides to give the corresponding cross-coupling products, unsymmetrical biaryls, in good to excellent yields.