Activating Metal Sites for Biological Electron Transfer.
Activating Metal Sites for Biological Electron Transfer.
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激活生物电子转移的金属位点。
DOI：
10.1002/ijch.201600016
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发表时间：
2016
影响因子：
3.2
通讯作者：
Snyder,BenjaminER
中科院分区：
文献类型：
--
作者：
Solomon,EdwardI;Hadt,RyanG;Snyder,BenjaminER
本文综述了蓝铜活性中心独特的光谱特征。这反映了一种新的电子结构，它激活了其生物功能中快速长距离电子转移的位点。蛋白质的作用，在确定该网站的几何和电子结构的定义，因为它的功能的贡献。这被称为吸能/齿条诱导状态。这些概念，然后扩展到cytochromec，这也被确定为在一个Entatic状态。
This review focuses on the unique spectroscopic features of the blue copper active sites. These reflect a novel electronic structure that activates the site for rapid long‐range electron transfer in its biological function. The role of the protein in determining the geometric and electronic structure of this site is defined, as is its contribution to function. This has been referred to as the entatic/rack‐induced state. These concepts are then extended to cytochromec, which is also determined to be in an entatic state.