Versatile synthesis of reversible comb-shaped supramolecular polymers
Versatile synthesis of reversible comb-shaped supramolecular polymers
复制标题
可逆梳形超分子聚合物的多功能合成
DOI：
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发表时间：
2014
期刊：
影响因子：
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通讯作者：
Laurent bouteillera
中科院分区：
文献类型：
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作者：
C. Fonteneau;Sandrine Pensec;Laurent bouteillera
我们报告了一种精确定义的氢键聚丙烯酸酯的模块化合成方法。在双官能ATRP（原子转移自由基聚合）引发剂中内置了各种各样的贴片，然后允许在链中间形成具有自互补贴片的聚丙烯酸酯，其摩尔质量可以在很大范围内调节（从3到100 kg mol−1）。通过FTIR和SANS在溶液中对这些自组装聚合物进行了表征，表明可以得到具有可逆主链的梳状超分子聚合物。
We report a modular synthesis method toward precisely defined hydrogen-bonded polyacrylates. Various stickers are built into difunctional ATRP (Atom Transfer Radical Polymerization) initiators, which then allow the formation of polyacrylates with self-complementary stickers in the middle of the chain, the molar mass of which can be tuned within a large range (from 3 to 100 kg mol−1). These self-assembling polymers are characterized by FTIR and SANS in solution, showing that comb-shaped supramolecular polymers with a reversible backbone can be obtained.
影响因子：
4.6
作者：
Herbst, Florian;Binder, Wolfgang H.
通讯作者：
Binder, Wolfgang H.