Visible Light-Induced Radical Rearrangement to Construct C-C Bonds via an Intramolecular Aryl Migration/Desulfonylation Process.

Visible Light-Induced Radical Rearrangement to Construct C-C Bonds via an Intramolecular Aryl Migration/Desulfonylation Process.
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DOI：
10.1021/acs.joc.6b00735
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发表时间：
2016-07
期刊：
The Journal of organic chemistry
影响因子：
--
通讯作者：
Yuyuan Li;Bei Hu;Wuheng Dong;Xiaomin Xie;Jun Wan;Zhaoguo Zhang
Yuyuan Li;Bei Hu;Wuheng Dong;Xiaomin Xie;Jun Wan;Zhaoguo Zhang
中科院分区：
其他
文献类型：
--
作者：
Yuyuan Li;Bei Hu;Wuheng Dong;Xiaomin Xie;Jun Wan;Zhaoguo Zhang

文献摘要

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利用可见光诱导的光氧化还原催化，实现了2-溴-N-芳基-N-（芳烃磺酰基）酰胺的高效分子内选择性芳基迁移/芳酰化反应。该方法允许在温和的反应条件下构建多种多取代的N，2-二芳基乙酰胺。
A highly efficient intramolecular selective aryl migration/desulfonylation of 2-bromo-N-aryl-N-(arenesulfonyl)amide via visible light-induced photoredox catalysis has been accomplished. This approach allows for the construction of a variety of multisubstituted N,2-diarylacetamide under mild reaction conditions.